Carbohydrates

Carbohydrates are organic molecules that contain carbon, oxygen and hydrogen and are the most abundant organic compounds in nature. They serve as forms of energy source and storage and structural components for plants and some animals [Champe]. They have the basic formula (CH₂O)_n hence the name Carbohydrate or hydrate of carbon. Important carbohydrates in brewing are simple sugars (e.g. glucose, fructose), complex sugars (e.g. maltose, sucrose, maltotriose), dextrins and starches. But glucans, pectins and gums are also carbohydrates.

The following sections give insight into the structure of carbohydrates important in brewing. Some are more and others (e.g. lactose and sucrose) are less important in mashing but may be used at other places in the brewing process.

Monosaccharides

Monosaccharides are the simples carbohydrates and have the basic formula C_nH_2nO_n. They are the building blocks of the more complex carbohydrates. The monosaccharides important to brewing, Glucose, Galactose and Fructose, are hexoses which contain 6 carbon atoms. They differ either in their carbonyl group or the orientation of the OH and H groups along the carbon chain. The carbonyl group is the group that contains the oxygen that is linked twice to a carbon atom. Either to the same carbon atom or tow different atoms from the same chain. Glucose and Galactose are adelose sugars and have an aldehyde group (Figures 1 and 3) as their carbonyl group and Fructrose is a ketose sugar and has a Ketone group (Figure 2).

Monosaccharides may exist in a open chain or in a ring configuration. But for monosaccharides with more than five carbons only less than one percent of the molecules will be in the open chain configuration. The rest is in the ring configuration. The rings are formed by the oxygen atom from the carbonyl group binding to another carbon atom of the chain.

By convetion the carbon atoms are numbered such that the highest numbered carbon is farthest away from the carbonyl (aldehyde or ketone) group.

Glucose

Figure 1 -

Glucose is by far the most important monosaccride in brewing. It is the building block for starch and thus produced during mashing. When the

Fructose

Figure 2 -

References

[Valclavik] Vickie A. Valclavik, Elizabeth W. Christian, Essentials of Food Science, Third Edition, Springer

[Champe] Pamela C, Champe, Richard A. Harvey, Denise R. Ferrier, Biochemistry, Lippincott's Illustrated Reviews

• types of sugar
• monosaccharides glucose, fructose, galctose
• disacchatrides maltose, succrose, lactose
• reducing/non reducing sugars
• where it is found
• glucose and 1-4/1-6 branches
• amylose
• amylopectin
• starch granule structure