Difference between revisions of "Troubleshooting Brewhouse Efficiency"
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− | Another factor for the achievable efficiency is the amount of grain and the preboil | + | Another factor for the achievable efficiency, aside from the lauter method, is the amount of grain and the preboil volume. The larger the grist in relation to the batch size, the more wort gets trapped in that grist after running off. As a result larger beers generally show a lower brewhouse efficiency. If more water is used for sparging, more of the extract can be washed out of the grain. The result is a higher brewhouse efficiency but also a higher preboil volume which requires longer or more intensive boiling. That and the increased sparging can be detrimental to the beer quality and should not be used to fix an efficiency problem. |
− | I would consider an efficiency (assuming a regular gravity beer: up to 1.060 / 16 Plato) that is below the ranges given above as problematic and worth investigating. | + | I would consider an efficiency (assuming a regular gravity beer: up to 1.060 / 16 Plato) that is below the ranges given above as problematic and worth investigating. Only when it is known where in the process the efficiency is lost a decision can be made about if and how the efficiency should be improved. While a low efficiency can be an indication of a suboptimal mashing and lautering process, A very high efficiency does not necessarily mean the best beer possible. The latter statement is targeted at oversparging which can lead to the excessive extraction of unwanted grain compounds (in particular tannins from the grain husks). |
=The concept of extraction and lauter efficiency= | =The concept of extraction and lauter efficiency= |
Revision as of 03:07, 10 September 2008
Work in progress
Rather than listing all the factors that can affect the brewhouse efficiency, this article is intended to provide a systematic approach to indentify and fix brewhouse efficiency shortcomings.
Contents
- 1 Determining the brewhouse efficiency
- 2 How good is my efficiency?
- 3 The concept of extraction and lauter efficiency
- 4 Determining extraction efficiency
- 5 Evaluating extraction efficiency
- 6 Determining Lauter efficiency
- 7 Sources
Determining the brewhouse efficiency
Before we can look for efficiency shortcomings and their causes we need to determine the efficiency. Since a number of different definitions for efficiency exist, it is possible that the actual efficiency is in a acceptable range but was calculated based on a different efficiency formula that returned a lower result. Other error factors are incorrect gravity or volume measurements.
In this analysis we will use the brew house efficiency into the boil kettle. Efficiency shortcomings after the boil (i.e. transfer to the fermenter) are obvious as they are proportional to the amount of wort that is left behind in the boil kettle. For a list of various efficiency definitions see the Understanding Efficiency.
Measuring and measurement errors
Before the efficiency can be calculated, 3 things need to be measured on brew day:
- amount of grain used
- specific gravity of the collected or finished wort
- volume of the collected or finished wort
It is important to be reasonably accurate when measuring these values. The more precise the measurements are, the more precise the calculated efficiency will be. As an example: If the grain weight has an error of 5% (which is +/- 200g for a 4.0kg grist or 0.5 lb for 10lb), the calculated efficiency will also have a 5% error, i.e. a calculated efficiency of 70% could actually be between 65% and 75%. The same applies to volume and gravity measurements.
The following measurement errors can be seen as reasonable:
- 1% error for the grain weight. This means +/- 40g for a 4.00 kg grist or 0.1 lb for 10 lb
- 2% error for the specific gravity. This means +/- 0.25 for 12 Plato or +/- 1 point for 1.050 SG
- 2% error on the volume measurement. This means +/- 0.5 on 25l or +/- 0.5 qt on 6 gal
and with them the efficiency can be calculated with a 5% accuracy.
Measuring Volumes
When measuring volumes on brewday, the temperature based expansion of water should be taken into account and all measured volumes should be corrected such that they represent the volume at room temperature. And since wort is mostly water, what is true for water is also true for wort. At 100 C or 212 F a given amount of water/wort has about 4% more volume than at room temperature. This means that 25 liter or quart 100C/212F hot wort is actually 24 liter or quarts. This is a difference of 1 liter or quart and fairly significant for precise efficiency calculations. But because it results in more volume than actual, it results in a higher than actual calculated efficiency. To correct a volume measurement made at near boiling or boiling temperatures, multiply with 0.96.
At mash and thus lauter temperatures ~ 70C / 160F the water/wort volume is only by about 3% larger than at room temperature. To correct a volume measurements, multiply with 0.97.
Also, take the time to calibrate or check the volume mesurement for the boil kettle. Be it a dip-stick or markings on the kettle. To be off by 1 qt for a 6 gal is a 4% error in the calculated efficiency.
Check the hydrometer
If you have already checked the calibration of the hydrometer you can proceed to Calculating Efficiency
To check the hydrometer use it in water at the calibration temperature that is noted on the scale. In water the hydrometer should read 1.000 or 0.0 Bailling/Brix/Plato. If another reference point is desired, dissolve 40g of table sugar in 160g of water. The resulting solution has a extract content of 20 Plato or 1.083 SG. But such a 2 point calibration is generally not necessary for hydrometers.
If the hydrometer doesn't read 1.000 SG or 0.0 Plato in water, it doesn't have to be thrown out. Simply remember to always subtract the difference to 1.000 SG or 0.0 Plato from every hydrometer reading.
Examples:
- If the hydrometer reads 1.002 in water, subtract 2 gravity points (i.e. 0.002) from every hydrometer reading
- If the hydrometer reads 0.998 in water, add 2 gravity points to every hydrometer reading
Calculating Efficiency
To calculate this efficiency two distinct approaches exist. The weight based approach calculates the weight of the extract that is present in the collected wort and puts it in relation to the total extract weight that was available in the grist. The gravity potential based approach puts the specific gravity that was achieved in relation to the maximum gravity potential that the grist has. Both approaches are explained below and either one can be chosen.
In addition to the two approaches shown here, the Batch-Sparging-Efficiency-Spreadsheet can also be used to calculate the brewhouse efficiency.
Weight based efficiency calculation
The weight based efficiency calculation is best done with metric measurements. If your measurements are not yet metric, please convert them using these formulas
- weight in kg = weight in lb * 0.45
- volume in liter = volume in gal * 3.78 = volume in quart * 0.95
- gravity in Plato = gravity points * 4 (this is simplified, but good enough for average specific gravities)
To calculate the efficiency, we need to calculate the amount of extract that is present in the collected wort. Because this amount doesn't change during the boil, unless additional malt extract or sugar is added during the boil, it doesn't matter if it is calculated based on pre or post boil measurements. Just make sure that the volumes are corrected for temperature (see above):
- kettle extract weight in kg = volume in liter * gravity in SG * gravity in Plato / 100
Multiplying the volume with the specific gravity of the wort, which is basically the kg/liter for the wort, gives the weight of the wort. That is then multiplied by the specific gravity given in Plato which expresses how much of that wort weight comes from extract (sugars, proteins, etc.).
The other weight that is needed is the weight of the extract that can theoretically be extracted from the grist. When a maltster tests the malty quality one of the properties determined is the fine grind extract. It is determined by grinding the malt to a flour and mashing it with a step mash program called a Congress Mash. After that the non dissolved matter is separated from the mash through multiple sparge steps such that 100%, or very close to that, of the extract that was made soluble ends up in the collected wort. The amount of extract in that wort is then determined and expressed as percent of the original grain weight. Luckily for us, the amount of extract present in the various grains (especially base malts) is fairly constant and we don't need to acquire a analysis sheet for all the malts that we used for our mash. Here is a table that lists commonly used types of malt and average fine grind extract percentages.
Malt type | fine grind extract content |
---|---|
2-row brewers malt | 80% |
6-row brewers malt | 78% |
Pilsner, Vienna, Munich | 80% [WEYERMANN, BEST MALZ] |
Pilsner Briess | 80% |
Munich malt Briess | 74-76% |
Specialty malts (crystal and roased) | 72 - 75 % [BRIESS, WEYERMANN] |
Carafa | 65% [WEYERMANN] |
oat, barley, corn and wheat flakes | 70% [BRIESS] |
rice flakes | 65% [BRIESS] |
The weight of extract in the grist is calculated as
- extract in grist in kg = weight of malt 1 in kg * fine grind extract grain 1 in % / 100 + weight of malt 2 in kg * fine grind extract grain 2 in % / 100 ...
If only little (<5%) specialty malts (crystal, roasted malts and Carfa) were used, the formula can be simplified to
- extract in grist in kg = weight of grist in kg * 0.8
The factor of 0.8 represents the average 80% extract content of most base malts.
Now that the weight of the extract in the collected wort and the weight of the extract initially present in the grain are known we can calculate the brewhouse efficiency as
- brewhouse efficiency in % = 100% * kettle extract weight in kg / extract in grist in kg
Dealing with kettle additions of sugars and/or extract
Some recipes require the addition of sugars or additional extract in the brew kettle. These additions can distort the calculated brewhouse efficiency if that efficiency is based on post boil measurements. To compensate for that, simply subtract the weight of the added sugar/extract from the calculated kettle extract weight before calculating the brewhouse efficiency. In case of liquid malt extract, subtract only 80% of the extract weight that was added. Or work with gravity and volume measurements that were taken before the sugar/extract was added.
Example
grist weight: 4.5 kg Pilsner malt cold post boil volume: 21 liter post boil gravity: 1.048 / 12 Plato kettle extract weight = 21 l * 1.048 * 12% / 100 = 2.64 kg extract weight in grist = 4.5 kg * 80% / 100 = 3.6 kg brewhouse efficiency = 100% * 2.64 kg / 3.6 kg = 73 %
Continue to How good is my efficiency? to see how this efficiency stacks up against commonly achieved brewhouse efficiencies.
Gravity potential based efficiency calculation
This type of calculation is best done with US units. If the measurements are not already available as such, used the followling fomulas to convert the numbers:
- volume in galons = volume in liter / 3.78
- gravity in gravity points = extract in Plato * 4
- weight in lb = weight in kg / 0.45
This calculation takes a different approach. It determines how many gravity points (the digits after the 1. in the specific gravity value) could one get from the given grist in the measured wort volume with 100% brewhouse efficiency. The actual brewhouse efficiency is then the actually achieved gravity points expressed as a percentage of that theoretical maximum. To calculate the theoretical maximum, we need to know the wort volume, the weight of the grist and the gravity potential (i.e. how many gravity points can be contributed) of that grist. The latter is expressed as points per pound and gallon (ppg) and can easily be derived from the fine grind extract percentage that is listed for malts. Pure table sugar is completely soluble and adding one pound of it to a volume of water that results in 1 gal of sugar solution will result in a solution with a specific gravity of 1.046. This means that sugar has a potential of 46 ppg. Malt and many adjuncts used in mashing are not completely soluble. Only their extractable weight (Fine grind extract) can me made soluble in mashing. To determine their gravity potential we simply multiply the gravity potential of sugar (46 ppg) with the fine grind extract percentage from the malt spec. This has been done in the following table
Malt type | fine grind extract content |
---|---|
2-row brewers malt | 37 ppg |
6-row brewers malt | 36 ppg |
Pilsner, Vienna, Munich | 37 ppg [WEYERMANN, BEST MALZ] |
Pilsner Briess | 37 ppg |
Munich malt Briess | 34-35 ppg |
Specialty malts (crystal and roased) | 33 - 35 ppg [BRIESS, WEYERMANN] |
Carafa | 30 ppg [WEYERMANN] |
oat, barley, corn and wheat flakes | 32 ppg [BRIESS] |
rice flakes | 30 ppg [BRIESS] |
Finally the theoretical maximum for the wort gravity is:
- maximum gravity points = (weight grain 1 in lb * potential grain 1 in ppg + weight grain 2 in lb * potential grain 2 in ppg ...) / volume in gal
If only a small amount of specialty grains were used, this simplified equation can be used
- maximum gravity points = weight of grist in lb * 37 ppg / volume in gal
To get the efficiency we put the actually measured gravity points in relation to the maximum gravity points
- brewhouse efficiency = 100% * actual gravity points / maximum gravity points
Dealing with kettle additions of sugars and/or extract
Some recipes require sugars or additional extract to be added in the brew kettle. These additions can distort the calculated brewhouse efficiency if that efficiency is based on post boil measurements. To compensate for that, simply subtract the gravity points gained from the added sugar/extract from the actual gravity points before calculating the brewhouse efficiency. The gravity points to subtract can be calculated as:
- gravity points from dry kettle extracts = extract weight in lb * 46 ppg / kettle voulme in gal
in case of liquid extract use 37 ppg since liquid extract is 80% extract and 20% water. Or work with gravity and volume measurements that were taken before the sugar/extract was added.
Example
grist weight = 10 lb (Pilsner malt) cold post boil volume = 5.5 gal post boil gravity = 1.048 (48 gravity points) maximum gravity points from grist = 10 lb * 37 ppg / 5.5 gal = 67.3 brewhouse efficiency = 100% * 48 / 67.3 = 71 %
How good is my efficiency?
Though a lot of opinions exist on what efficiency numbers are good and which ones are bad, let me try to give some guidelines in assessing the brewhouse efficiency. The following table lists a range of brewhouse efficiencies that can be expected from various brewing systems:
brewing system | typical brewhouse efficiency range |
---|---|
Large scale commercial brewing | 92 - 98 % [HUPPMANN] |
Fly sparging | 80 - 95% |
Batch sparging | 75% - 90% |
No sparge | 65% - 80% |
Another factor for the achievable efficiency, aside from the lauter method, is the amount of grain and the preboil volume. The larger the grist in relation to the batch size, the more wort gets trapped in that grist after running off. As a result larger beers generally show a lower brewhouse efficiency. If more water is used for sparging, more of the extract can be washed out of the grain. The result is a higher brewhouse efficiency but also a higher preboil volume which requires longer or more intensive boiling. That and the increased sparging can be detrimental to the beer quality and should not be used to fix an efficiency problem.
I would consider an efficiency (assuming a regular gravity beer: up to 1.060 / 16 Plato) that is below the ranges given above as problematic and worth investigating. Only when it is known where in the process the efficiency is lost a decision can be made about if and how the efficiency should be improved. While a low efficiency can be an indication of a suboptimal mashing and lautering process, A very high efficiency does not necessarily mean the best beer possible. The latter statement is targeted at oversparging which can lead to the excessive extraction of unwanted grain compounds (in particular tannins from the grain husks).
The concept of extraction and lauter efficiency
There are 2 main processes that affect the brewhouse efficiency: mashing and lautering/sparging. Mashing is a mainly chemical process in which the extractable portion of the grain is made soluble through enzymatic and physical processes. The result is a mash liquid in which sugars, proteins and other compounds (the sum of all that is called extract) from the grain have been dissolved. During the lautering/sparging, a physical process, is this extract transferred to the boil kettle while the insoluble parts of the grain (husks, cell wall structure of the endosperm, coagulated protein, etc.) are left behind. Both processes are influences by different factors and should be evaluated separately from each other. Because of that I want to introduce the following formula for brewhouse efficiency:
- brewhouse efficiency = extraction efficiency * lauter efficiency
Determining extraction efficiency
To determine the extraction efficiency we simply need to measure the gravity (i.e. extract content) of the mash liquid once the mash is complete. Based on the amount of mash liquid that was used and the amount of extract that was potentially extractable from the grain, we can determine what the extract concentration in the mash should be for 100% extraction efficiency. Use the following formula or the table (take from understanding efficiency) on the right to calculate the first wort extract content or specific gravity that would be achieved with 100% extraction efficiency
- first wort extract = extract in grist in kg / (extract in grist in kg + water used in l)
Calculating the specific gravity of the first wort based on the gravity potential of the grist is more complicated since the volume to be used in that equation is not the volume of the water used but the volume of the resulting wort which is larger due to the dissolved extract and more difficult to measure. The easiest way is to calculate the water grist ratio and use table XX.
The extraction efficiency is the ratio between the actual extract content (Plato) or specific gravity of the first wort and the first wort extract/gravity calculated for 100% extraction efficiency.
- extraction efficiency = 100% actual fisrt wort extract in Plato / calculated first wort extract
or
- extraction efficiency = 100% * (actual first wort SG – 1) / (calculated first wort SG -1)
The Batch Sparging Analysis spreadsheet can also be used to calculate the extraction efficiency from the grist weight, water used and first wort extract/gravity.
The extraction efficiency should be close to 100% as this is an indication that all mash parameters (crush, temperature, pH, time, diastatic power, water/grist ratio, mash schedule) were in the correct range for full conversion. Weather or not they were in the correct range for other worth parameters (e.g. fermentability) cannot be determined at this point. If the extraction efficiency is satisfactory proceed to “Determining lauter efficiency”, otherwise read on to learn about parameters that affect the extraction efficiency.
Evaluating extraction efficiency
If the extraction efficiency is less than 90-95%, test the wort and spent grain for starch with iodine. Wort is best tested for starch on a piece of chalk or drywall and to test the spent grain pick up a few pieces, rub them between two fingers and add a drop of iodine solution. If they turn black-purple, they still contain starch (Wash hands afterwards). If there is still starch in the spent grain it is oftentimes the case that you can still see dry starch in the middle of larger grits of endosperm. Unconverted starch can have multiple reasons:
- crush: If the crush is to coarse, the pieces of endosperm will be to large for the gelatinization and enzymes to convert them at the chosen saccrification temperature and time. Evaluate the crush. Are there any uncrushed kernels? Are there any kernels that are cracked, but the endosperm doesn't come out easily? But keep in mind, that there is a limit in how much a tighter crush can improve extraction efficiency (especially if other mash parameters are off as well) and that it can be overdone. From I experience I suggest a crush done with a mill gap spacing between 0.5 and 0.8 mm.
- temperature: While any temperature below the upper temperature limit for the amylase enzymes (about 80C/175F) can lead to full conversion, only temperatures between ~63C/145F and 80C/175F are known to fully convert a mash within a practical saccrification rest time mash time. The exact temperature that should be chosen for the saccrification rest depends on the mash schedule, rest time, attenuation target and diastatic power of the malt. Check your thermometer against another one or at least against ice water (0C/32F) and boiling water (100C/212F; if you are close to see level).
- pH: the enzymes that are responsible for the starch conversion are not only sensitive to temperature, but they are also sensitive to the mash pH. The brewing literature and small scale mashing experiments show that the mash pH should be between 5.3 and 5.7 (measured at room temperature) for optimal extraction efficiency. The mash pH is determined by the water/mash's mineral content and the gist composition. Check your RA with John Palmer's residual alkalinity spreadsheet or, even better, check the mash pH. You won't need to buy a pH meter for this, using precision test strips like EMD's colorpHast strips are good enough.
- diastatic power: This can be a problem with grists that contain large amount of highly kilned malts or unmalted grains. Highly kilned malts are lower in enzymes because the kilning process damaged more of them and the use of unmalted grains (e.g. rice or corn) dilutes the enzymatic power of the mash because they add only a small amount, if any, enzymes to the mash. If the amount of enzymes in the mash is low, the mash may not be able to convert itself or the working ranges for the other mash parameter got much smaller. A mash with a low enzyme content may just need more time or a different mash schedule (step mash v.s. Single infusion mash) to be able to fully convert. If this is suspected to the the culprit, choose a different mash schedule or replace some of the enzymatic weaker malt with enzymatic stronger (e.g. Pale or Pilsner) malt.
- time: The longer the mash rests while the enzymes are still active, the more of the starch can be converted. Once all starch has been converted time will not have an effect on the extraction efficiency anymore. But it may still have an effect on other wort properties like fermentability for example which is why we don't just stop mashing once the mash is converted. When mashing at lower temperatures or with enzymatic weak grists, extending the saccrification rest length from 60min to 90min or longer may just do the trick for getting to complete conversion and satisfiable extraction efficiency.
- water/grist ratio: The gelatinization and enzymatic activity requires free water and in order to be fully completed, enough water needs to be available. This sets the lower limit of water/grist ratio for mashing. According to Briggs this lower limit is around 2 l/kg or 1 qt/lb [Briggs, 2004]. If to much water exists in the mash the enzymes may be to spread out to efficiently work on the starch. But that only happens at very thin mashes. It has been reported that even mashes as thin as 5 l/kg or 2.5 qts/lb work well. Based on that it is unlikely that a mash was to thin for conversion.
- mash schedule: Enzymatic weak mashes, mashes with undermodified malt (which is hard to find these days) or adjunct mashes may not fully convert when using the simple single infusion mash schedule. For such mashes it may be necessary to boil some of the grains/malt (decoction or cereal mashes) or use different saccrification rest temperatures. For enzymatic weak mashes it may be beneficial to add a dextrinization rest between 70C/158F and 75C/166F to speed up the alpha amylase and get the last bit of starch converted.
Determining Lauter efficiency
There 2 ways to determine the Lauter efficiency. If batch sparging is used, it can be estimated from the total amount of water that was used and the total volume of water that was used to create that wort. For fly and batch sparging it can also be estimated from measuring the extract that is still left in the grains after sparging.
Calculating Lauter efficiency (batch sparging)
The concept of calculating the lauter efficiency for batch sparging has been demonstrated in Batch Sparging Analysis. As this is a rather involved an cumbersome process I suggest taking accurate measurements of:
- grain weight and extract content of that grain (see above)
- total water volume used for mashing and sparging measured at room temperature. This does not include water added to compensate for decoction boil off if applicable.
- the total volume of wort collected and the temperature at which it was measured.
- the extract content (Plato) or specific gravity of the wort that was collected. Make sure the wort is well mixed to prevent wort stratification.
- If even higher precision for the calculation is desired you can also note the collected wort volumes and temperatures after each run-off. If that is not done, equal run-off sizes will be assumed.
And then using the Batch-Sparging-Efficiency-Analysis spreadsheet to calculate the theoretical lauter efficiency.
Evaluating the batch sparging lauter efficiency
If the theoretical lauter efficiency isn't close to the lauter efficiency determined from the extraction efficiency and brewhouse efficiency, the batch sparging process was suboptimal. Have a look at the following:
- Was the mash thoroughly stirred after the addition of grain? It is easily possible for a tick portion of the mash to remain undisturbed at the bottom or in corners of the mash/lauter tun.
- Were the measurements done correctly or did you forget about water additions or wort that was collected but not added to the brew kettle?
- Did the mash drain completely before new sparge water was added? Though that is not necessary for batch sparging, it was assumed for the calculation of the batch sparge lauter efficiency.
Run-off speed and rest time after stirring the mash don't have any impact on the lauter efficiency in batch sparging.
Testing the lauter efficiency (fly and batch sparging)
--- concept not yet tested ----
To some extend, the lauter efficiency can also be measured. This measurement tries to estimate the amount of extract left in the grain by diluting it with a known amount of water and measuring the extract/gravity of the resulting wort. Based on that the percentage of extract that remained in the lautertun can be estimated. While a more detailed formula can be found in [Understanding Efficiency], a simple table is used here.
To use that table to estimate use the following procedure:
- add 0.5, 1.0, 1.5 or 2.0 quart of water per pound of initial grist weight. This water doesn't have to be hot. Cold tap water works just fine. You are not going to make beer from this, this is just for testing purposes. Make sure the mash is thin enough to be stirred very well. For metric measurements add 1 or 2 l/kg grist weight
- stir the mash well making sure to get the mash stuck in corners and at the bottom of the lautertun
- take a gravity or hydrometer reading of the mash liquid
- temperature correct that reading and look it up in the table. The number in the column corresponding to the amount of water that was added shows the brewhouse percentage lost in the mash. Subtract that from the extraction efficiency to find the lauter efficiency.
To calculate this table it was assumed that the girst had an average laboratory extract of 80%, which corresponds to an extract potential of 37 ppg, and a wort absorption rate of 0.19 gal/l or 1.58 l/kg.
Example
grist weight = 10 lb (Pilsner malt) amount of water added = 10 qt mash liquid SG = 1.006 extraction efficiency = 95% The amount of water added corresponds to 1 qt/lb. For that amount and a mash liquid SG of 0.6 we find that 7% of the brewhouse efficiency were lost in the spent grain (i.e. 7% of the extract available in the grain were left in the spend grain as sugars dissolved in the wort).But only 95% of the grain extract were dissolved to begin with. This means that 95% - 7% = 88% must be the extract that made it into the boil kettle. Hence the lauter efficiency is the amount in the boil kettle (88%) divided by the amount that was dissolved at the start of the lauter (95%) which is a lauter efficiency of 92%.
Evaluating Lauter efficiency
If the lauter efficiency is much less than 90% for fly sparging to many dissolved sugars were left in the spent grain. This is likely to be the result of channeling. An effect where the sparge water doesn't rinse the grain bed evenly but finds paths of least resistance (channels). Causes of this can be a rushed run-off (the slower the better the sparge water will be able to rinse the sugars from the grains) or an inadequate manifold design. If the latter is the case, batch sparging may better be suited for the lauter tun.
Sources
- [BRIESS 2008] Briess average malt analysis data 2007/2008 PDF
- [HUPPMANN] brosure for the Hupmann Lauterstar lauter tun design PDF
- [WEYERMANN] Malzfabrik Weyermann malt specifications ZIP
- [BEST MALZ] Best Malz Malzqualitaeten